I believe Tunebots come with general numeric guidelines for basic batter and reso head settings. To find your sound, you have to experiment from that jumping off point.
Here's a very broad overview of tom tuning, not taking into account overall pitch:
Reso head tuned tighter than the batter
Reso head tuned looser than the batter
Reso head tuned the same as the batter
It's all personal preference. Experiment with all three options.
By how much the reso is looser or tighter than the batter is where you will be experimenting. First, you get the batter head feel you like, mushy, tight, or in between. Then work on the reso. There's a lot of different tunings to go through trying to figure out the exact batter/reso tuning relationship that you go for. For instance I like my reso a full octave above my batter head note for a pitch bend tone. People use the intervals of 3rd, 4th, and 5th between heads with equally good results too.
Me, I don't like the reso looser than the batter as I feel it sounds boingy. But it is used by lots of drummers, so it's all preference. Find yours.
If you find you prefer the batter and reso tuned the same, you will be experimenting with what pitch sounds best to you for that drum.
I definitely try and tune to discernable notes with definite intervals, so when I run down the toms, pitch-wise, my kit "resolves". You don't have to, you make your own tuning rules..
After you know how you like to tune one drum, IMO the harder part of tuning is to tune the set so all the drums sound like they are tuned together.
It's fairly easy to get one drum sounding good. Making 4 or 5 drums work together pitch-wise takes effort.
My suggestion is to focus on spending time learning and experimenting how to tune the 12" tom to your liking. Then transfer your preferences to the other toms.
Bass drum tuning is a different subject, as is snare tuning.